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991.
Alecos Demetriades Xiangdong Li Michael H. Ramsey Iain Thornton 《Environmental geochemistry and health》2010,32(6):529-552
In the Lavrion urban area study, Hellas, a five-step sequential extraction method was applied on samples of ‘soil’ (n = 224), affected by long-term mining and metallurgical activities, and house dust (n = 127), for the purpose of studying the potential bioaccessibility of lead and other metals to humans. In this paper, the
Pb concentrations in soil and house dust samples are discussed, together with those in rocks and children’s blood. Lead is
mainly associated with the carbonate, Fe–Mn oxides and residual fractions in soil and house dust. Considering the very low
pH of gastric fluids (1–3), a high amount of metals, present in soil (810–152,000 mg/kg Pb) and house dust (418–18,600 mg/kg Pb),
could be potentially bioaccessible. Consequently, children in the neighbourhoods with a large amount of metallurgical processing
wastes have high blood-Pb concentrations (5.98–60.49 μg/100 ml; median 17.83 μg/100 ml; n = 235). It is concluded that the Lavrion urban and sub-urban environment is extremely hazardous to human health, and the
Hellenic State authorities should urgently tackle this health-related hazard in order to improve the living conditions of
local residents. 相似文献
992.
Jiang He Chang-Wei Lü Hong-Xi Xue Ying Liang Saruli Bai Ying Sun Li-Li Shen Na Mi Qing-Yun Fan 《Environmental geochemistry and health》2010,32(1):45-58
This paper analyses the contents and species distributions of rare earth elements (REEs) in the water-suspended particulate-sediment
system of the Baotou section of the Yellow River, China, with known anthropogenic REE input from industrial discharges. The
major forms of REEs were suspended and dissolved in the mainstream and the tributaries of the Baotou section, respectively.
The concentrations of the dissolved and suspended REEs had the same trends in the overlying water along the mainstream, which
increased from the Seqi section (site A) to the mouth of the Sidaosha River (site D), reaching a maximum value at site D,
and tending to decrease thereafter. The contents of REEs in sediment cores showed enrichment with light rare earth elements
(LREEs). The bound to carbonates and to Fe–Mn oxides are the major forms of REE in the secondary phase and the REE exhibited
LREE enrichment pattern and moderate Eu depletion in suspended particulates and surface sediments. The contents and species
distributions of REEs in the water-suspended particulate-sediment system of the Baotou section suggest that the anthropogenic
source of REEs from Baotou city have enhanced REE accumulation to the Baotou section. This information is important for predicting
possible pollution resulting from anthropogenic REE input into rivers. 相似文献
993.
Hydrogeochemical considerations about the origin of groundwater salinization in some coastal plains of Elba Island (Tuscany,Italy) 总被引:1,自引:0,他引:1
Elena Giménez-Forcada Alberto Bencini Giovanni Pranzini 《Environmental geochemistry and health》2010,32(3):243-257
Several coastal plains of the Elba Island (Marina di Campo, Portoferraio, Schiopparello, Mola, Porto Azzurro and Barbarossa
plains) in Tuscany (Italy) were studied to determine the causes of decline in groundwater quality, using major ion chemistry
to establish the causes of groundwater salinization. The study demonstrates that salinization of coastal plain alluvial aquifers
is not simply linked to seawater intrusion but is also intimately related to inflows from adjacent aquifers. Ionic ratios,
correlation graphs and distribution value maps were employed as the means to understand the hydrochemistry of the study areas.
The Mg/Cl ratio in particular can be considered a good tracer to distinguish the main salinization processes that control
groundwater chemistry. Seawater intrusion only partly determines the chemistry of some groundwaters, which generally belong
to a chloride facies where the salinity is derived principally from freshwater–seawater mixing and the participation of cation
exchange. Proceeding inland groundwater quality seems to be principally determined by the inflow of Mg, Ca-HCO3 or Ca, Na-HCO3 waters formed from the weathering of silicate minerals in adjoining aquifers. Hydrolysis of these minerals is of prime importance
in controlling groundwater chemistry in adjacent alluvial plains. The lateral recharge flows introduce water with a different
chemical composition and this variable of freshwater recharge changes the hydrochemistry as a result of mixing between two
or more waters types. This situation is further complicated when seawater and base exchange reactions participate, due to
seawater intrusion. 相似文献
994.
Ryoko Fujiyoshi Yukihide Haraki Takashi Sumiyoshi Hikaru Amano Ivan Kobal Janja Vaupotič 《Environmental geochemistry and health》2010,32(1):73-82
Radon (222Rn) and carbon dioxide were monitored simultaneously in soil air under a cool-temperate deciduous stand on the campus of Hokkaido
University, Sapporo, Japan. Both 222Rn and CO2 concentrations in soil air varied with atmospheric (soil) temperature in three seasons, except for winter when the temperature
in soil air remained constant at 2–3°C at depth of 80 cm. In winter, the gaseous components were influenced by low-pressure
region passing through the observation site when the ground surface was covered with snow of ~1 m thickness. Carbon isotopic
analyses of CO2 suggested that CO2 in soil air may result from mixing of atmospheric air and soil components of different origins, i.e. CO2 from contemporary soil organic matter and old carbon from deeper source, to varying degrees, depending on seasonal meteorological
and thus biological conditions. 相似文献
995.
Arsenic (As) contamination has become a serious environmental problem in many countries. We have performed batch-type leaching
experiments on mine tailing soils collected from three abandoned mine areas in South Korea with the objective of evaluating
the effect of indigenous bacterial activity on As mobilization. The analysis of physicochemical properties and mineralogical
compositions of the samples indicated that the secondary minerals or phases formed as a result of the oxidation or alteration
of primary minerals were associated with the labile and bioleachable fractions of As. Compared to simulated abiotic processes
using sterilization, the indigenous bacteria activated using a carbon source were able to enhance the dissolution of As under
both aerobic and anaerobic conditions. The bacterial dissolution of iron (Fe) and manganese (Mn) was found to occur simultaneously
with the dissolution of As, suggesting that the main bacterial mechanism was via the dissimilatory reduction of Fe(III),
Mn(IV), and As(V). An anaerobic environment was more favorable for the prominent dissolution of As in the tailing soils. These
results indicate that the mobilization of As can be enhanced in the oxygen-depleted part of the tailing dump, particularly
with the infiltration of organic substrates. The difference in the degree of As lixiviation between the three tailing soils
was found to be related to the bioavailability of As as well as the original biomass in the tailing soils. 相似文献
996.
Enver Guler Deniz Ozakdag Muserref Arda Mithat Yuksel Nalan Kabay 《Environmental geochemistry and health》2010,32(4):335-339
The effect of feed seawater temperature on the quality of product water in a reverse osmosis process was investigated using
typical seawater at Urla Bay, Izmir region, Turkey. The tests were carried out at different feed seawater temperatures (11–23°C)
using two RO modules with one membrane element each. A number of variables, including pH, conductivity, total dissolved solids,
salinity, rejection percentage of a number of ions (Na+, K+, Ca2+, Mg2+, Cl−, HCO3
−, and SO4
2−), and the levels of boron and turbidities in collected permeates, were measured. The suitability of these permeates as irrigation
and drinking water was checked by comparison with water quality standards. 相似文献
997.
Anthropogenic influence on surface water quality of the Nhue and Day sub-river systems in Vietnam 总被引:2,自引:0,他引:2
Pham Thi Minh Hanh Suthipong Sthiannopkao Kyoung-Woong Kim Dang The Ba Nguyen Quang Hung 《Environmental geochemistry and health》2010,32(3):227-236
In order to investigate the temporal and spatial variations of 14 physical and chemical surface water parameters in the Nhue
and Day sub-river systems of Vietnam, surface water samples were taken from 43 sampling sites during the dry and rainy seasons
in 2007. The results were statistically examined by Mann–Whitney U-test and hierarchical cluster analysis. The results show that water quality of the Day River was significantly improved during
the rainy season while this was not the case of the Nhue River. However, the river water did not meet the Vietnamese surface
water quality standards for dissolved oxygen (DO), biological oxygen demand (BOD5), chemical oxygen demand (COD), nutrients, total coliform, and fecal coliform. This implies that the health of local communities
using untreated river water for drinking purposes as well as irrigation of vegetables may be at risk. Forty-three sampling
sites were grouped into four main clusters on the basis of water quality characteristics with particular reference to geographic
location and land use and revealed the contamination levels from anthropogenic sources. 相似文献
998.
Increasing polybrominated diphenyl ether (PBDE) contamination in sediment cores from the inner Clyde Estuary,UK 总被引:1,自引:0,他引:1
Christopher H. Vane Yun-Juan Ma She-Jun Chen Bi-Xian Mai 《Environmental geochemistry and health》2010,32(1):13-21
The concentrations of 16 polybrominated diphenyl ether (PBDE) congeners in six short sediment cores from the Clyde Estuary
were determined by gas-chromatography mass-spectrometry. Total PBDE concentrations ranged from 1 to 2,645 μg/kg and the average
concentration was 287 μg/kg. BDE-209 was the main congener and varied from 1 to 2,337 μg/kg. Elevated total PBDE concentrations
were observed close to the sediment surface in the uppermost 10 cm of four of the six sediment cores. Comparison of the down
core PBDE profiles revealed that the increase was driven by the accumulation of deca-BDE. Although the deca-BDE mix was dominant,
the presence of lower molecular weight congeners BDE-47, BDE-99, BDE-183 and BDE-153 at most sediment intervals suggested
additional sources of penta-BDE and octa-BDE pollution. Changing PBDE source input was the major factor in influencing the
proportion of nona-brominated congeners, although other explanations such as post burial photo-debromination of BDE-209 cannot
be entirely discounted. A clear cascading to lower hepta-, hexa-, and penta-homologues was not found. The increase in total
PBDE concentrations and particularly the deca-BDE may possibly be ascribed to the use and subsequent disposal of electrical
appliances such as televisions and computers. In the Clyde sediments, the proportion of nona-brominated congeners was higher
than that reported for commercial mixtures. This might be due to changing sources of PBDEs or post burial photo-debromination
of BDE-209. 相似文献
999.
Amini Hassan Haghighat Gholam Ali Yunesian Masud Nabizadeh Ramin Mahvi Amir Hossein Dehghani Mohammad Hadi Davani Rahim Aminian Abd-Rasool Shamsipour Mansour Hassanzadeh Naser Faramarzi Hossein Mesdaghinia Alireza 《Environmental geochemistry and health》2016,38(1):25-37
Environmental Geochemistry and Health - There is discrepancy about intervals of fluoride monitoring in groundwater resources by Iranian authorities. Spatial and temporal variability of fluoride in... 相似文献
1000.
Jinglan Feng Pengtuan Hu Fei Zhang Jianhui Sun 《Environmental geochemistry and health》2016,38(6):1241-1253
The levels, potential sources and ecological risks of hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethanes (DDTs) in Yellow River of Henan section, a typical agricultural area in China, were investigated. Surface water samples and suspended particulate matters (SPMs) were collected from 23 sites during two seasons. In wet season, the residues of ∑HCHs (α-HCH, β-HCH, γ-HCH and δ-HCH) and ∑DDTs (p,p′-DDT, o,p′-DDT, p,p′-DDE, p,p′-DDD) ranged from 41.7 to 290 and 4.42 to 269 ng/L in surface water, while those varied from 0.86 to 157 and 1.79 to 96.1 ng/g dw in SPM, respectively. Moreover, in surface water, the levels of HCHs and DDTs in wet season were much higher than those in dry season. The reverse was true for residues of HCHs and DDTs in SPM. Compared with the large rivers in other regions, the levels of HCHs and DDTs in the studied area ranked at high levels and the residual concentrations might cause adverse biological risk, especially for ∑HCHs during wet season. Distributions of HCHs and DDTs delineated that the input of tributaries made a significant effect on the residue of HCHs and DDTs in the mainstream. ∑HCHs in surface water were consist of 26.7 % α-HCH, 30.0 % β-HCH, 37.9 % γ-HCH and 5.45 % δ-HCH and those in SPM contained 5.16 % α-HCH, 22.1 % β-HCH, 60.5 % γ-HCH and 12.2 % δ-HCH on average. Combined with ratios of α-HCH/γ-HCH in surface water (0.70) and in SPM (0.09), the results strongly indicated that lindane was recently used or discharged in the studied area. The mean percentage of DDTs′ isomers were 28.7 % p,p′-DDT, 29.8 % o,p′-DDT, 28.1 % p,p′-DDE and 13.4 % p,p′-DDD in surface water, while those were 12.5 % p,p′-DDT, 31.8 % o,p′-DDT, 30.5 % p,p′-DDE and 25.1 % p,p′-DDD in SPM. The ratios of (DDE + DDD)/∑DDTs and o,p′-DDT/p,p′-DDT revealed that the DDTs in the studied area mainly derived from long-term weathering of technical DDTs residue and the input of dicofol. 相似文献